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Assuming the guy at (listen to the podcast!) http://www.radicalrc.com/blog/?p=82 is correct: (and assuming I wrote it down correctly) ((Ah * vBatt) / vReg) * (SBEC efficiency% / 100) = Ah available after regulation where
so according to that calculation the 3S will last slightly longer. All theoretical of course, and at this sort of difference you're probably better off with whichever is the lighter setup and just charge between flights or swap packs, whatever suites you. Not forgetting that you don't want to use more than 70% to 80% of the available battery capacity anyway, else you risk damaging the pack.
just for fun, what about a 1350mAh 3S pack?
(1.35*11.1) / 5 = 2.997 * 0.85 = 2.54745 Ah
wow! that is a big step up over the 2S